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Synthesis 1990; 1990(6): 525-527
DOI: 10.1055/s-1990-26928
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Synthese α-C-glucosylierter α-Aminocarbonsäure-Derivate

Gerhard Simchen* , Eckhardt Pürkner
  • *Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität Stuttgart, Pfaffenwaldring 55, D-7000 Stuttgart 80, Federal Republic of Germany
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Publication Date:
17 September 2002 (online)

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Synthesis of α-C-Glucosylated Derivatives of α-Amino Carboxylic Acids α-C-Glucosylation of amino acids was achieved by the reaction of ketene acetals 3 with the α-glucosyl bromide 4b in presence of zinc bromide to yield the β-anomers of the α-glucosyl-α-amino acid derivatives 6.