Synthesis 1990; 1990(9): 850-852
DOI: 10.1055/s-1990-34093
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Vicarious Nucleophilic Substitution of Hydrogen in Nitroarenes by Carbanions of Alkyl Dichloroacetates. Some New Transformations of Chloro(nitroaryl)acetates

Mieczysław Makosza* , Krzysztof Sienkiewicz, Krzysztof Wojciechowski
  • *Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, PL-01-224 Warsaw, Poland
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Publication History

Publication Date:
17 September 2002 (online)

Vicarious Nucleophilic Substitution of Hydrogen in nitroarenes by ethyl dichloroacetate anion provides ethyl chloro(nitroaryl)acetates, which can be transformed into ethyl imino(nitroaryl)acetates and ethyl oxo(nitroaryl)acetates by treatment with sodium azide.