PDF herunterladen
Synthesis 1991; 1991(5): 395-398
DOI: 10.1055/s-1991-26475
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Durch (Lig)Ni(0) induzierte Herstellung von mono- und di-Carbonsäuren aus Cyclopenten und Kohlendioxid

Heinz Hoberg* , Alfredo Ballesteros, Andrei Sigan, Corine Jegat, Armin Milchereit
  • *Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330 Mülheim a. d. Ruhr, Germany
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
29. April 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

(Lig)Ni(0) Induced Preparation of Mono- and Dicarboxylic Acids from Cyclopentene and Carbon Dioxide Cyclopentene is shown to be an ideal substrate for coupling reactions with (Lig)nickel(0) systems. By variation of the ligands and addition of promotors, it is possible by successive application of carbon dioxide or carbon monoxide to prepare highly selectively series of cyclopentane- and cyclopentenecarboxylic acids (six examples), 4, 5, 6, 11, 14, 15, cyclopentanedicarboxylic acids (three examples), 7, 8,12, or 2-hydroxycyclopentanecarboxylic acid (9) in good yields. The C5-skeleton is retained in the products.