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Synthesis 1991; 1991(6): 454-456
DOI: 10.1055/s-1991-26491
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A Convenient Synthesis of S-Alkyl O-Aryl Thiophosphoric Acid Derivatives

Chu-Chi Tang* , Gui-Ping Wu, Gen-Zhu Zhang
  • *Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, People's Republic of China
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Publikationsdatum:
29. April 2002 (online)

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A new convenient synthesis of S-alkyl O-aryl thiophosphoric acid derivatives is reported. The chlorination of O-aryl O,O-dialkyl thiophosphates with phosphorus oxychloride proceeds with isomerization to give S-alkyl Oaryl thiophosphorochloridates, which react further with various nucleophiles in the presence of base to give the title compounds.