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Synthesis 1991; 1991(7): 581-582
DOI: 10.1055/s-1991-26521
DOI: 10.1055/s-1991-26521
paper
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Homolytic Acylation of Methyl 3-Amino-2-pyrazinecarboxylates
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Publication History
Publication Date:
29 April 2002 (online)
Homolytic acylation of methyl 3-amino-2-pyrazinecarboxylates 1a-c under standard Minisci conditions affords the corresponding 5- or 6-monoacylated pyrazines 3a-d or 4a,b in reasonable yields. With 1a, complete selectivity in favor of the 5-acyl products is observed.