PDF herunterladen
Synthesis 1991; 1991(11): 954-958
DOI: 10.1055/s-1991-28531
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Mild Approach to N-Acylformamidines and C-Acylamidines by the Facile Reduction of Carbodiimides with Pentacoordinated Silicon Hydrides

Robert  * , J. P. Corriu, Gérard F. Lanneau, Myriam Perrot-Petta
  • *Laboratoire Hétérochimie et Amino-Acides, associé au CNRS no 1097, Université des Sciences et Techiques du Languedoc Case 007, Place Eugène Bataillon, F-34095 Montpellier Cedex 05, France
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
29. April 2002 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

N 1-Acyl-, N 1-aryl-N 2-arylformamidines 4 and N 1,N 2-dialkyl C-acylamidines 6 result from the acylation of the N 1-silylformamidines 2a and C-silyl amidines 2b,c respectively. The latter are obtained by the hydrosilylation of aryl- and alkylcarbodiimides with the pentacoordinated silicon hydride 1.