Download PDF
Synthesis 1992; 1992(4): 387-390
DOI: 10.1055/s-1992-26119
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Isomerisierung von kristallinen 1,2,3-Tris(arylmethylen)cyclohexanen zu 1,2,3-Tris(arylmethyl)benzolen durch gasförmigen Bromwasserstoff

Herbert Frey*
  • *Organische Chemie I, Fachbereich Chemie, Universität Oldenburg, Postfach 2503, D-2900 Oldenburg, Germany
Further Information

Publication History

Publication Date:
17 September 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

1,2,3-Tris(arylmethylene)cyclohexanes (eleven examples) are prepared by aldol condensation from aromatic aldehydes and cyclohexanones, followed by Wittig olefination. They are rearranged nearly quantitatively by gasous hydrogen bromide to 1,2,3-tris(arylmethyl)benzenes.