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Synthesis 1992; 1992(10): 954-956
DOI: 10.1055/s-1992-26276
DOI: 10.1055/s-1992-26276
short paper
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An Easy One-Pot Synthesis of Group 14 C-Metallated 2 (or 3)-Furan- and Thiophenecarbaldehydes
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Publikationsverlauf
Publikationsdatum:
17. September 2002 (online)
The group 14 C-metallated 2(or 3)-furan- and thiophenecarbaldehydes 4-19 have been regioselectively prepared by a one-pot procedure from the corresponding furan- and thiophenecarbaldehydes using lithium N-methylpiperazide/butyllithium or sec-butyllithium/chlorotrialkylsilanes (germanes, tin)/water as sequence of reagents.