PDF herunterladen
Synthesis 1992; 1992(10): 972-976
DOI: 10.1055/s-1992-26282
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Chiral Ligands Containing Heteroatoms; 9.1 General Procedures for the Synthesis of Optically Active 1-(2-Pyridyl)alkylamines from α-Amino Acids

Massimo Falorni* , Giorgio Chelucci, Sandra Conti, Giampaolo Giacomelli
  • *Dipartimento di Chimica, Università di Sassari, Via Vienna 2, I-07100 Sassari, Italy
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
17. September 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

General syntheses of 1-(2-pyridyl)alkylamines and N-methyl or N,N-dimethyl-1-(2-pyridyl)alkylamines from optically active α-amino acids are described. The presented procedures are based on catalyzed co-cyclotrimerization of the suitable nitriles with acetylene which can be conducted without loss of optical purity.