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Synthesis 1992; 1992(12): 1199-1200
DOI: 10.1055/s-1992-26331
short paper
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Dithio and Thiono Esters; 581. α-Azido-Substituted Dithio and Thioacetates

Klaus Hartke* , Andreas Brutsche
  • *Institut für Pharmazeutische Chemie der Universität Marburg, Marbacher Weg 6, D-3550 Marburg/Lahn, Germany
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Publication Date:
29 April 2002 (online)

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Azidoacetonitrile (1) reacts with an alcohol or thiol and hydrogen chloride to form 1-alkoxy[1-alkylthio]-2-azidoethan-l-iminium chlorides (Pinner salts) 3 which are sulfhydrolyzed to give O-alkyl azidothioacetates 4a,b and alkyl azidodithioacetates 4c,d.