Asymmetric Epoxidation with Optically Active (Salen)manganese(III) Complexes: From Which Direction Does the Olefin Approach the Metal-Oxo Bond?

Naoki Hosoya; Akira Hatayama; Koichi Yanai; Hiroyuki Fujii; Ryo Irie; Tsutomu Katsuki

doi:10.1055/s-1993-22554

Synlett 1993; 1993(9): 641-645
DOI: 10.1055/s-1993-22554

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Asymmetric Epoxidation with Optically Active (Salen)manganese(III) Complexes: From Which Direction Does the Olefin Approach the Metal-Oxo Bond?

Naoki Hosoya^* , Akira Hatayama, Koichi Yanai, Hiroyuki Fujii, Ryo Irie, Tsutomu Katsuki

^*Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812, Japan