Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1993; 1993(8): 785-787
DOI: 10.1055/s-1993-25941
DOI: 10.1055/s-1993-25941
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Highly Efficient Chromium-Catalyzed Oxidation of Secondary Benzylic Alcohols by Aqueous 70% tert-Butyl Hydroperoxide
Further Information
Publication History
Publication Date:
27 September 2002 (online)
![](https://www.thieme-connect.de/media/synthesis/199308/lookinside/thumbnails/10.1055-s-1993-25941-1.jpg)
The oxidation of secondary benzylic alchols to ketones by the chromium(VI) oxide/tert-butyl hydroperoxide system is compatible wih the presence of methyl, halide, methoxy, acetoxy or nitro substituents on the aryl group and of an unsaturation on the alkyl side chain. Benzyl alchol led to a mixture of benzaldehyde and benzoic acid.