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Synthesis 1993; 1993(9): 909-919
DOI: 10.1055/s-1993-25968
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Pair-Wise Interactions by Gas Chromatography; Part III:1,2 Synthesis of Isosteric Stationary Phases for Gas Chromatography

Roland Cloux* , Guy Défayes, Klára Fóti, Jean-Claude Dutoit, Ervin Sz. Kováts
  • *Laboratoire de Chimie Technique de I'Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland
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Publication Date:
29 April 2002 (online)

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Retention in gas/liquid partition chromatography depends on the size and, to a lesser extent, on the form of the solvent used as stationary phase. How the measurement of interaction free enthalpies between a functional group and a solute free of size and form effects synthesis and properties of seven high molecular weight solvents is described. The monofunctional paraffin derivatives have the same form and nearly the same molar volume as that of their parent alkane 19,24-dioctadecyldotetracontane.