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Synthesis 1993; 1993(12): 1267-1270
DOI: 10.1055/s-1993-26040
DOI: 10.1055/s-1993-26040
paper
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Synthesis of C25- and C26-Steroid Carboxylic Acids from C22-Steroids Using Nickelacycles as Propionic and Butyric Acid Equivalents
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Publikationsverlauf
Publikationsdatum:
29. April 2002 (online)
C25- and C26 -steroid carboxylic acids as well as their methyl esters with different rings A and B were synthesized with good to excellent yields from C22 -iodides 1 using the nickelacycles 2a and 2b as propionic and butyric acid equivalents.