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Synlett 1994; 1994(8): 647-648
DOI: 10.1055/s-1994-22960
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Catalysis by Lithium Perchlorate in Diethyl ether : Intramolecular Diels-Alder Reaction of Nitrotrienes

Alain GUY* , Laurence SERVA
  • *Laboratoire de Chimie Organique (ER X 0077) Conservatoire National des Arts et Metiérs 292, rue Saint-Martin 75141 PARIS Cedex 03 (France)
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Publication Date:
18 September 2002 (online)

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Concentrated solution of lithium perchlorate in diethylether catalyzes the intramolecular Diels-Alder reaction of the cyclenic nitrotrienes 4a-b giving rise to one stereoisomer from endo selectivity.