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Synlett 1994; 1994(11): 949-951
DOI: 10.1055/s-1994-23060
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Synthesis of Allylsilanes by Palladium(0) Catalyzed Reduction of Trialkylsilylallyl Esters.

Jean Ollivier* , Jacques Salaün
  • *Laboratoire des Carbocycles, URA 478 du CNRS, Institut de Chimie Moléculaire d'Orsay, Bât. 420, Université de Paris-Sud, 91405 Orsay, France
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Publication Date:
22 March 2002 (online)

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Palladium (0) catalyzed reduction of trialkylsilylallyl esters by hydrides from HCOONa or n-BuZnCI (ß-elimination) led to allylsilanes as major products, offering a new and stereoselective access to these useful electrophilic reagents.