Phenylation of Alkenyl Triflates: Reaction with Tetrabutylammonium Difluorotriphenylstannate.

A. García Martínez; J. Osío Barcina; A. de Fresno Cerezo; L. R. Subramanian

doi:10.1055/s-1994-23081

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Synlett 1994; 1994(12): 1047-1048
DOI: 10.1055/s-1994-23081

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Phenylation of Alkenyl Triflates: Reaction with Tetrabutylammonium Difluorotriphenylstannate.

A. García Martínez^* , J. Osío Barcina, A. de Fresno Cerezo, L. R. Subramanian

^*Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain

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Publication Date:
22 March 2002 (online)

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The reaction of alkenyl triflates 1 with tetrabutylammonium difluorotriphenylstannate catalyzed by Pd(PPh₃)₄ affords regio and stereospecifically the corresponding alkenylbenzenes ₂ in excellent yields.