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Synthesis 1994; 1994(2): 176-180
DOI: 10.1055/s-1994-25433
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One-Pot Synthesis of α-Trimethylsilyl Enones from Vinylsilanes

Waldemar Adam* , Markus J. Richter
  • *Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany
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Publication Date:
17 September 2002 (online)

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Photooxygenation of vinylsilanes in the presence of acetic anhydride and pyridine afforded α-trimethylsilyl enones 1 in moderate to good yields. Since the required starting materials are readily available, the present approach constitutes a useful alternative to existing methods for the preparation of α-trimethylsilyl enones 1.