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Synthesis 1994; 1994(2): 185-189
DOI: 10.1055/s-1994-25435
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Novel Routes for the Synthesis of Upper Rim Amino and Methoxycarbonyl Functionalized Calix[4]arenes Carrying Other Types of Functional Groups

Peter Timmerman* , Willem Verboom, David N. Reinhoudt, Arturo Arduini, Stefania Grandi, Anna R. Sicuri, Andrea Pochini, Rocco Ungaro
  • *Laboratory of Organic Chemistry, University of Twente, NL-7500 AE Enschede, The Netherlands
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Publication Date:
17 September 2002 (online)

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The selective functionalization of calix[4]arenes 1 by iodination at the upper rim in the presence of other functionalities is described. The resulting (partly) iodinated calix[4]arenes 2 are good starting materials for the preparation of both the corresponding carboxylic ester and amino derivatives 3 and 6, respectively.

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