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Synthesis 1994; 1994(2): 199-202
DOI: 10.1055/s-1994-25438
DOI: 10.1055/s-1994-25438
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Nucleophilic Aromatic Substitution Reactions of 1-Methoxy-2-(diphenylphosphinyl)naphthalene with C-, N-, and O-Nucleophiles: Facile Synthesis of Diphenyl(1-substituted-2-naphthyl)phosphines
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Publikationsdatum:
17. September 2002 (online)
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A novel nucleophilic aromatic substitution reaction is described in which the methoxy group of 1-methoxy-2-(diphenylphosphinyl)-naphthalene is readily replaced with Grignard reagents, alkoxides, and amides. Reduction of the resulting phosphine oxides provides a convenient route to diphenyl(1-substituted-2-naphthyl)phosphines.