Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1994; 1994(3): 313-316
DOI: 10.1055/s-1994-25467
DOI: 10.1055/s-1994-25467
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Stereospecific Synthesis of Trisubstituted Alkenyl(phenyl)iodonium Salts from Vinylstannanes
Further Information
Publication History
Publication Date:
27 September 2002 (online)
![](https://www.thieme-connect.de/media/synthesis/199403/lookinside/thumbnails/10.1055-s-1994-25467-1.jpg)
A simple and efficient stereospecific synthesis of alkenyl(phenyl)iodonium tosylates 5a-5e and triflates 6a-6g from reaction between cyano(phenyl)iodonium tosylate (4a) or triflate (4b) and the corresponding vinylstannanes 3a-3g is described. The reaction affords 55 to 90% yields of stereodefined products with retention of the vinylstannane geometry.