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Synthesis 1994; 1994(6): 552-554
DOI: 10.1055/s-1994-25520
short paper
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Reactions of (Z)-α,β-Didehydroamino Aldehydes with Ethyl Diethylphosphonoacetate, Ethyl Acetate, and Trimethylsilyl Cyanide

Yutaka Nakamura* , Chung-gi Shin
  • *Laboratory of Organic Chemistry, Faculty of Technology, Kanagawa University, Rokkakubashi, Kanagawa-ku, Yokohama 221, Japan
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Publication Date:
17 September 2002 (online)

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In order to explore the reactivity of (Z)-α, β-didehydroamino aldehydes, Wittig-Horner reaction with ethyl diethylphosphonoacetate, aldol condensation with ethyl acetate, and cyanohydrin reaction with trimethylsilyl cyanide were tried successfully to give the corresponding dienocarboxylate, enolcarboxylate, and cyanohydrin derivatives, respectively, in good yields.