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Synthesis 1994; 1994(6): 609-612
DOI: 10.1055/s-1994-25533
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A Convenient Synthesis of β,γ-Unsaturated Carboxylic Acid Derivatives via Carbonylation of (η3-Allyl)Fe(CO2NO Complexes

Saburo Nakanishi* , Takeshi Yamamoto, Naoyuki Furukawa, Yoshio Otsuji
  • *Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture, 1-1 Gakuen-cho, Sakai, Osaka 593, Japan
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Publikationsdatum:
17. September 2002 (online)

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One-pot reaction of allyl halides with [Bu4N]+[Fe(CO)3(NO)]- followed by treatment with 1,2-bis(diphenylphosphino)ethane gave βγ-unsaturated acyl iron complexes in good yields via regioselective carbonylation with retention of configuration of the allylic double bond. β,γ-Unsaturated carboxylic acid esters and amides were prepared upon treatment of the acyl iron complexes with alcohols and amines in the presence of iodine.