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Synthesis 1994; 1994(6): 624-628
DOI: 10.1055/s-1994-25536
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Deoxygenation of Aliphatic Alcohols via Reduction of New Thioxocarbamate Derivatives

Makoto Oba* , Kozaburo Nishiyama
  • *Department of Material Science and Technology, Tokai University, 317, Nishino, Numazu, Shizuoka 410-03, Japan
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Publication Date:
17 September 2002 (online)

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N-Acylthioxocarbamates, obtained by the reaction of alcohols with acyl isothiocyanates, were reduced by tributylstannane or triphenylsilane under radical conditions to give deoxygenated products of the corresponding alcohols in good yields. An application to regioselective deuteration using tributyldeuteriostannane is also examined.