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Synthesis 1994; 1994(9): 920-922
DOI: 10.1055/s-1994-25604
short paper
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Convenient Synthesis of Substituted 1-Chlorocyclopropanecarboxylic Acids

J. L. Coudret* , K. Ernst, A. de Meijere, B. Waegell
  • *Laboratoire de Stéréochimie, associé au CNRS-URA 1409, Faculté des Sciences St-Jérôme, Av. Escadrille Normandie-Niemen, F-13397 Marseille Cedex 20, France and Institut für Organische Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, D-37077 Göttingen, Germany
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Publication Date:
17 September 2002 (online)

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Catalytic oxidation of various substituted 1-chloro-1-trichloroethenylcyclopropanes 1a-i with ruthenium tetroxide generated in situ produces the corresponding 1-chlorocyclopropanecarboxylic acids 2a-i in good yields (78 to 95%).