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Synthesis 1994; 1994(12): 1445-1449
DOI: 10.1055/s-1994-25711
DOI: 10.1055/s-1994-25711
paper
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Synthesis and Reactions of Thioether-Thiolate Compounds of 1,3-Dithiole-2-thione-4,5-dithiolate (dmit)
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Publikationsdatum:
25. April 2002 (online)
An efficient method for the preparation of the unsymmetrically substituted 1,3-dithiole-2-thione-4,5-dithiolate (dmit) is reported. Its application is demonstrated by obtainment of various 1,3-dithiole-2-thione-4-thiolate-5-thioesters and ethers. Starting from these compounds an expedient route to novel unsymmetrical crown compounds and tetrathiafulvalenes is shown.