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Synthesis 1995; 1995(5): 515-517
DOI: 10.1055/s-1995-3946
short paper
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Potassium Fluoride-Poly(Hydrogen Fluoride) Salts as Fluorinating Agents for Halofluorination of Alkenes

Masanori Tamura* , Motonari Shibakami, Akira Sekiya1
  • *National Institute of Materials and Chemical Research, 1-1 Higashi, Tsukuba, Ibaraki 305, Japan, Fax +81(298)544487
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Publication Date:
31 December 2000 (online)

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It was found that potassium fluoride-poly(hydrogen fluoride) salts are useful fluorine sources for halofluorination of alkenes. The reaction proceeded with these salts and N-halosuccinimides or 1,3-dibromo-5,5-dimethylhydantoin in a regio- and stereoselective manner.

potassium fluoride-poly(hydrogen fluoride) salts - fluorinating agent - halofluorination - alkene