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Synthesis 1995; 1995(5): 475-497
DOI: 10.1055/s-1995-3957
DOI: 10.1055/s-1995-3957
review
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π Stacking Effects in Asymmetric Synthesis
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
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The effects and benefits of π stacking in asymmetric synthesis is reviewed. Specifically, asymmetric induction achieved with chiral auxiliaries and chiral catalysts can be enhanced by π stacking effects, locking one confirmation of a reactant preferentially in a given transition state assembly. The evolution of such systems, their application in synthesis, together with related developments in the field of molecular recognition will be highlighted.
π stacking - asymmetric synthesis - enantioselective catalysts - chiral auxiliaries - molecular recognition