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Synthesis 1995; 1995(6): 671-674
DOI: 10.1055/s-1995-3973
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New Efficient Synthesis of 4-Amino-3-arylphenols

A. Avenoza, J. H. Busto, C. Cativiela* , J. M. Peregrina
  • *Department of Organic Chemistry, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-C.S.I.C., E-50009 Zaragoza, Spain, Fax +34(9)76567920
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Publication Date:
31 December 2000 (online)

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Treatment in an alkaline medium of the cycloadducts obtained from the Diels-Alder cycloaddition of Danishefsky’s diene with different oxazol-5(4H)-ones constitutes an efficient method for the aromatisation of the cyclohexene ring, allowing the synthesis of 3-substituted 4-aminophenols, by previous hydrolysis of the benzamide group.

5(4H)-oxazolones - Danishefsky’s diene - Diels-Alder - 3-aryl-4-amino-phenols