Download PDF
Synthesis 1995; 1995(8): 952-956
DOI: 10.1055/s-1995-4020
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of Di- or Tetrafunctionalized Phosphorus Macrocycles

Joëlle Mitjaville, Anne-Marie Caminade, Jean-Pierre Majoral*
  • *Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, F-31077 Toulouse Cedex, France, Fax +33(61)553003
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

The reaction of functionalized phosphodihydrazides RP(X)[NMeNH2]2 (R=Cl, N3) (1) with organic (2) or phosphorus (4) dialdehydes leads to the synthesis of di- or tetrafunctionalized phosphorus macrocycles 3a-d, 5a-h in good yield. PCl containing macrocycles are quantitatively converted to PN3 containing macrocyclic with sodium azide. All compounds are useful precursors of cryptands and multimacrocyclic species.

Functionalized phosphorus macrocycles precursors of cryptands and multimacrocyclic species

      >