PDF herunterladen
Synthesis 1995; 1995(9): 1071-1073
DOI: 10.1055/s-1995-4055
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Trichloronitromethane with Acyl Chlorides in the Presence of Tin(II) Chloride: Synthesis of Trichloronitro Ketones

Ayhan S. Demir* , Cihangir Tanyeli, Hilal Aksoy, Volkan Gulbeyaz, Ali S. Mahasneh
  • *Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey, Fax +90(312)2101280; E-mail asdemir@rorqual.cc.metu.edu.tr
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Trichloronitromethane adds to acid chlorides in the presence of tin(II) chloride to yield dichloronitro ketones via a substitution reaction. Reduction and dechlorination of the dichloronitro ketones give dichloroamino alcohols and nitro ketones, respectively, in good yield.

The reaction of trichloronitromethane with acid chlorides gives the dichloronitro ketones