Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml
Synthesis 1995; 1995(11): 1348-1350
DOI: 10.1055/s-1995-4120
DOI: 10.1055/s-1995-4120
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
An Efficient Procedure for Palladium-Catalyzed Reduction of Aryl/Enol Triflates
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synthesis/199511/lookinside/thumbnails/10.1055-s-1995-4120-1.jpg)
An efficient procedure to deoxygenate phenols and enols via trifluoromethanesulfonates is presented. Their reduction with triethylsilane in the presence of a catalytic amount of palladium acetate and bidentate phosphine ligands such as 1,3-bis(diphenylphosphino)propane or 1,1’-bis(diphenylphosphino)ferrocene proceeds efficiently to afford a variety of aromatic, heteroaromatic, and olefinic compounds.
reduction - aryl/enol triflates - palladium-catalyzed reaction - triethylsilane