Synthesis 1995; 1995(10): 1287-1290
DOI: 10.1055/s-1995-4434
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Boron Trifluoride-Diethyl Ether Complex Catalyzed Aromatic Amino-Claisen Rearrangements

Wayne K. Anderson* , Gaifa Lai
  • *Department of Medical Chemistry, School of Pharmacy, State University of New York at Buffalo, Buffalo, New York 14260, USA
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Boron trifluoride-diethyl ether complex (BF3⋅OEt2) was demonstrated to be an efficient catalyst for the amino-Claisen rearrangements of various aromatic N-allylamines into the corresponding o-allylamines in moderate yields.