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Synlett 1995; 1995(4): 361-362
DOI: 10.1055/s-1995-4961
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Cerium-mediated Conjugate Additions of a Difluorophosphonate Carbanion to Nitroalkenes

T. P. Lequeux, J. M. Percy*
  • *School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK
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Publication Date:
31 December 2000 (online)

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We report a general cerium-mediated procedure that allows the conjugate addition of a difluoromethylenephosphonate carbanion to a range of nitroalkenes derived from non-aromatic aldehydes.

Difluorophosphonate - conjugate addition - organocerium reagent - nitroalkene

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