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Synlett 1995; 1995(6): 628-630
DOI: 10.1055/s-1995-5039
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A New Method for Synthesis of Acetylenes and Olefins through Cross Coupling of Aldehydes

Tsuneo Sato, Hiroshi Tsuchiya, Junzo Otera*
  • *Department of Applied Chemistry, Okayama University of Science, Ridai-cho, Okayama 700, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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Unsymmetrically substituted acetylenes and olefins are obtained by coupling aldehyde with dithioacetal followed by phenylthiomigration and elimination.

acetylene - olefin - aldehyde - dithioacetal - cross coupling