Synthesis of Exo-enynes by Ruthenium-Catalyzed Cross Coupling Reaction of Hydroxy Allenes and 1-Alkynes

Masahiko Yamaguchi; Yoshiyuki Kido; Kenji Omata; Masahiro Hirama

doi:10.1055/s-1995-5229

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Synlett 1995; 1995(11): 1181-1182
DOI: 10.1055/s-1995-5229

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Synthesis of Exo-enynes by Ruthenium-Catalyzed Cross Coupling Reaction of Hydroxy Allenes and 1-Alkynes

Masahiko Yamaguchi^* , Yoshiyuki Kido, Kenji Omata, Masahiro Hirama

^*Department of Chemistry, Graduate School of Science, Tohoku University, Aoba, Sendai, 980-77, JAPAN

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Publication Date:
31 December 2000 (online)

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RuH₂(PPh₃)₄ and ferrocenylphosphines catalyze cross coupling reaction of hydroxy allenes and 1-alkynes giving exo-enynes selectively.

hydroxy allenes - alkynes - ferrocenylphosphines - RuH₂(PPh₃)₄ - exo-enynes