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Synlett 1995; 1995(12): 1229-1231
DOI: 10.1055/s-1995-5253
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Diastereoselective Reduction of α-(p-Tolylsulfinyl)ketoximes

Kazuyuki Miyashita, Tomohiro Toyoda, Hideto Miyabe, Takeshi Imanishi*
  • *Faculty of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565, Japan
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Publication History

Publication Date:
31 December 2000 (online)

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α-Sulfinylketoximes were stereoselectively reduced by L-Selectride to give (S)-(N-methoxyamino)sulfoxides, which is the first successful example for diastereoselective reduction of α-sulfinylimino derivatives via a ”nonchelate model”.

α-(p-tolylsulfinyl)ketoxime - diastereoselective reduction - L-Selectride - nonchelate model - optically active amine