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Synthesis 1996; 1996(1): 25-27
DOI: 10.1055/s-1996-4170
short paper
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Simple Synthesis of Enantiomerically Pure, Protected cis-Bicyclo[4.4.0]decane-1-carboxaldehyde Derivatives from Cyclohexanones by the 3-Arenesulfonyloxazolidine Route

Olaf Prien, Dieter Hoppe*
  • *Institut für Organische Chemie der Universität Münster, Corrensstraße 40, D-48149 Münster, Germany, Fax +49(251)839772
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Publication Date:
31 December 2000 (online)

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The preparation of several enantiomerically pure, functionalized cis-Bicyclo[4.4.0]decane systems from cyclohexanone by the 3-arenesulfonyloxazolidine route is reported.

diastereoselective Robinson annulation - 2-acyl-3-tosyl-1,3-oxazolidines - cis-bicyclo[4.4.0]decanes