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Synthesis 1996; 1996(2): 204-208
DOI: 10.1055/s-1996-4199
DOI: 10.1055/s-1996-4199
paper
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Synthesis of Alkynyl-Substituted Pyrrolidin-1-yloxyl Radicals from 1-Pyrroline N-Oxide Nitrones and Alkynylmagnesium Bromides
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
The reaction of 1-pyrroline N-oxides with propargyl- and alkynylmagnesium bromides proceed to give alkynyl functionalized pyrrolidin-1-oxyls without the formation of isoxazolines by a dipolar cycloaddition reaction.
Synthesis of alkynyl-substituted pyrrolidin-1-oxyl radicals via Grignard reaction.