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Synthesis 1996; 1996(3): 333-335
DOI: 10.1055/s-1996-4213
short paper
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Two-Carbon Homologation of Grignard Reagents to Primary Amines

Krystyna Osowska-Pacewicka, Andrzej Zwierzak*
  • *Institute of Organic Chemistry, Technical University (Politechnika), Żwirki 36, PL-90924 Łódź, Poland, Fax +48(42)365530
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Publikationsdatum:
31. Dezember 2000 (online)

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A novel, convenient synthesis of N-(diethoxyphosphoryl)aziridine is described. Application of this compound as a synthetic equivalent of an a2 type synthon for aminoethylation of Grignard reagents is demonstrated.

A general aminoethylation of Grignard compounds is reported.