PDF herunterladen
Synthesis 1996; 1996(4): 467-469
DOI: 10.1055/s-1996-4234
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Simple and High Yield General Route to Methyl α-Oxo Thiolcarboxylates

Iacopo Degani, Stefano Dughera, Rita Fochi* , Antonella Gatti
  • *Istituto di Chimica Organica dell’Università, via P. Giuria 7, I-10125 Torino, Italy, Fax +39(11)6707642
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Methyl α-oxo thiolcarboxylates (aliphatic, aromatic and heteroaromatic) are obtained in good to excellent yields by hydrolysis of the corresponding trimethyl α-oxo trithioorthoesters with N-bromosuccinimide in aqueous THF or with HgO/35% aqueous HBF4 ves.

α-keto thiolcarboxylates - α-keto trithioorthoesters - hydrolysis