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Synthesis 1996; 1996(5): 609-613
DOI: 10.1055/s-1996-4255
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Preparation of New Octopus Shaped Homoleptic and Heteroleptic Ruthenium(II)-Bisdiazine Complexes

M. Kropf, H. Dürr* , C. Collet
  • *Fachbereich 11.2 Organische Chemie der Universität des Saarlandes, 66041 Saarbrücken, Germany, Fax +49(681)3024105
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Publikationsdatum:
31. Dezember 2000 (online)

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The preparation of RuL3 (1), RuL2L’ (2) and Ru(pod) (3) complexes containing polyethylene glycol chains is described. The complexes are further functionalized by 4-oxyanisyl or by hydrophilic hydroxyl groups. These new complexes may interact in supramolecular assemblies with suitable acceptors such as mono- and bisviologens to form biomimetic models for photosynthesis.

ruthenium complexes - bipyridazine - polyethylene glycol supramolecular multidentate binding - electron transfer