Download PDF
Synthesis 1996; 1996(8): 949-953
DOI: 10.1055/s-1996-4323
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of Phenolic Biaryls and p-Terphenyls and Their Heteroaromatic Analogs via a Cycloaddition Route Using 4-Aryl-2-silyloxybuta-1,3-dienes and Electron-Deficient Alkynes

Yoshihiko Yamamoto, Keiko Nunokawa, Masatomi Ohno, Shoji Eguchi*
  • *Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464-01, Japan, Fax +81(52)7893199
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A one-pot synthesis of phenolic biaryls and p-terphenyls by a [4+2] cycloaddition of 4-aryl-2-silyloxybuta-1,3-dienes with electron-deficient alkynes followed by oxidative aromatization of the resulting cycloadducts is reported.

4-aryl-2-silyloxybuta-1,3-diene - electron-deficient alkyne - Diels-Alder reaction - oxidative aromatization - biphenyl