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Synthesis 1996; 1996(8): 986-990
DOI: 10.1055/s-1996-4329
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A Short Synthesis of 2,3-Di(hetero)arylpyrido[3,2-f]thiazepines

Axel Couture* , Eric Deniau, Pierre Grandclaudon, Cristian Simion
  • *Laboratoire de Chimie Organique Physique, URA CNRS N° 351, Université des Sciences et Technologies de Lille, F-59655 Villeneuve d’Ascq Cédex, France, Fax +3320436561
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Publication Date:
31 December 2000 (online)

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A reaction sequence leading to the new title compounds is described, the key step of which is the treatment of anions of N-arylmethyl(2-chloropyridyl) methylidene amines with aromatic and heteroaromatic O-ethyl thiocarboxylates.

2-azaallyl anions - O-ethyl thiocarboxylates - annulation - pyrido[3,2-f][1,4]thiazepines - electrocyclic reactions

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