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Synthesis 1996; 1996(9): 1087-1089
DOI: 10.1055/s-1996-4339
short paper
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Titanium-Mediated Aldol-Tishchenko Reaction: A Stereoselective Synthesis of Differentiated anti 1,3-Diol Monoesters

Rainer Mahrwald* , Burkhard Costisella
  • *Fachbereich Chemie der Humboldt-Universität Berlin, Hessische Straße 1-2, D-10115 Berlin, Germany
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Publication Date:
31 December 2000 (online)

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anti 1,3-Diol monoesters were obtained in a high level of stereoselectivity by a one-pot aldol-Tishchenko reaction of ketones with aldehydes using substoichiometric amounts of titanium ate complexes.

one-pot aldol-Tishchenko reaction - anti 1,3-diol monoesters - titanium ate complexes - acyl migration - anti 1,3-diol