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Synthesis 1996; 1996(10): 1217-1222
DOI: 10.1055/s-1996-4370
DOI: 10.1055/s-1996-4370
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Synthesis and Properties of 2,6-Substituted Push-Pull Azulenes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
Red colored 2,6-disubstituted push-pull aminoazulenecarboxylates were prepared in very good yields from 2,6-azulenedicarboxylate, the key compound in this synthesis, which was prepared in four steps from 2-indancarboxylic acid. Effects of the push-pull substituents on the azulenes were analyzed by NMR and UV-visible spectroscopy.
2,6-substituted azulenes - carbene addition - Curtius reaction - UV-visible spectra of red azulenes