Photochemical Synthesis of Macrocycles

Axel G. Griesbeck; Andreas Henz; Joachim Hirt

doi:10.1055/s-1996-4400

Synthesis 1996; 1996(11): 1261-1276
DOI: 10.1055/s-1996-4400

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Photochemical Synthesis of Macrocycles

Axel G. Griesbeck^* , Andreas Henz¹ , Joachim Hirt¹

^*Institut für Organische Chemie der Universität zu Köln, Greinstr. 4, D-50939 Köln, Germany, Fax +49(221)4705057

Abstract

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Photochemical methods are described by which macrocyclic ring systems can be synthesized. Ring transformations, cyclization and substitution reactions which are initiated by homolytic cleavage or by electron transfer steps are highly valuable for the design and generation of complex medium- and large-ring molecules.

macrocycles - photochemistry - CH-activation - photo electron transfer

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