Synthesis of Disaccharides by Selective Metallocene Promoted Activation of Glycosyl Fluorides

M. Isabel Barrena; Raouf Echarri; Sergio Castillón

doi:10.1055/s-1996-5554

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Synlett 1996; 1996(7): 675-676
DOI: 10.1055/s-1996-5554

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Synthesis of Disaccharides by Selective Metallocene Promoted Activation of Glycosyl Fluorides

M. Isabel Barrena, Raouf Echarri, Sergio Castillón^*

^*Department de Química, Universitat Rovira i Virgili, Pça. Imperial Tarraco 1, 43005 Tarragona, Spain

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Publication Date:
31 December 2000 (online)

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The Cp₂HfCl₂/AgX (X=OTf, ClO₄)system is able to activate ”armed” glycosyl fluorides in the presence of ”disarmed” ones and this effect has been used in a direct synthesis of disaccharides.

Glycosyl fluorides - glycosylation - disaccharides - metallocene