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Synlett 1996; 1996(9): 845-846
DOI: 10.1055/s-1996-5609
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Reactions of a New Sorensen-type Nucleophile with Organoiron Complexes: Synthesis of N-Deprotected, Diastereomerically Pure Amino Acids

Richard D. A. Hudson, Simon A. Osborne, G. Richard Stephenson*
  • *School of Chemical Sciences, University of East Anglia, Norwich, NR4 7TJ, U.K.
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Publication Date:
31 December 2000 (online)

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We describe the preparation of a new head group 8 for use in amino acid synthesis, and its application in the formation of a series of diastereomerically pure (in all but one case), N-deprotected, α-tricarbonyl(cyclohexadiene)iron(0)-amino acids.

Organoiron - amino acid - ketene silylacetal - Sorenson-type nucleophile - stereoconvergent decarboxylation