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Synlett 1996; 1996(12): 1213-1214
DOI: 10.1055/s-1996-5722
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Construction of Palladium-Polypyrrole Catalytic System in the Wacker Oxidation

Masayoshi Higuchi, Satoshi Yamaguchi, Toshikazu Hirao*
  • *Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565, Japan, Fax (+81) 6 879 7415, hirao@chem.eng.osaka-u.ac.jp
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Publication Date:
31 December 2000 (online)

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A complex system consisting of palladium(II) acetate and polypyrrole is effective in the catalytic Wacker oxidation, indicating that polypyrrole serves as a redox-active ligand to form a reversible redox cycle under oxygen.

palladium catalyst - polypyrrole - redox-active ligand - the Wacker oxidation